モレキュラーシーブ

人工合成水和ケイ酸塩(ゼオライト)で、分子作用をスクリーニングする天然ゼオライトです。その化学レシピは(M′2 M)O·Al 2O3·xSi O 2·yH2Oであり、M′とMはK+、Na+、Ca 2+、Ba 2+などの一価および二価の陽イオンです。その構造には、均一な直径を持つ多数の細孔と整然と配置された空洞があります。分子篩の異なる細孔径は、異なるサイズと形状の分子を分離します。Si O 2とAl 2O3の分子比に応じて...
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分子ふるいは、四面体二酸化ケイ素とアルミナ構造を持つ結晶性金属アルミニウムケイ酸塩で、三次元の相互接続ネットワークを形成します。加熱により、均一な空洞が生成され、特定のサイズの分子を選択的に吸着して、このネットワークから天然の水和水を除去します。4ー8メッシュサイズの

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Sievesは通常、気相アプリケーションに使用され、8ー12メッシュサイズのふるいは一般的に液相アプリケーションに使用されます。3 A、4 A、5 A、13 Xふるいの粉末形態は、特定のアプリケーションに適しています。

Molecularふるいは、乾燥能力(90°Cまで)で長年にわたって有名であり、最近では合成有機プロセスで実用性が示されています。通常、望ましい生成物を、不利な平衡によって制御される縮合反応から分離することができます。これらの合成ゼオライトは、ケチミンやアミン縮合、エステル縮合、不飽和アルデヒドからポリアルデヒドへの変換などのシステムから、水、アルコール(メタノールやエタノールを含む)、塩酸を除去することが証明されています。

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Molecularふるいは、精密で均一な微小な細孔を含む材料であり、気体や液体を吸着するために使用できます。通常、分子ふるいはアルミニウムシリケート鉱物で構成されており、合成混合物や化合物もあります。これらの化合物は、粘土、多孔質ガラス、微多孔質炭、活性炭などの小分子が拡散できる開放構造を持っています。


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Molecularふるいは、細孔径よりも小さい分子を細孔の内部チャネルに吸着し、細孔外の大きな分子をはじくことができます。これにより、分子をスクリーニングする機能を果たすことができます。もちろん、モレキュラーシーブはスクリーニングの機能を持つだけでなく、反応能力を高めるための特定の役割を持っています。つまり、化学反応において「媒体」として機能し、化学反応の進行を促進します。




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