غربال مولکولی

یک سیلیکات هیدراته مصنوعی مصنوعی (زئولیت) با عملکرد مولکولی غربالگری یا زئولیت طبیعی. فرمول شیمیایی آن (M ‘2M) O · Al2O3 · xSiO2 · yH2O است که در آن M‘ و M کاتیون های تک ظرفیتی و دو ظرفیتی مانند K + ، Na + و Ca2 + ، Ba2...
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جزئیات محصول

غربال های مولکولی سیلیکات های آلومینیومی فلزی کریستالی با دی اکسید سیلیسیم چهار وجهی و ساختارهای آلومینا هستند که یک شبکه به هم پیوسته سه بعدی را تشکیل می دهند. با حرارت دادن ، حفره های یکنواختی تولید می شود که به طور انتخابی مولکول هایی با اندازه های خاص را جذب می کند و در نتیجه آب هیدراته طبیعی را از این شبکه حذف می کند.

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Sieves با اندازه های مش 4 تا 8 معمولاً در کاربردهای فاز گاز استفاده می شود ، در حالی که غربال هایی با اندازه مش 8 تا 12 معمولاً در کاربردهای فاز مایع استفاده می شود. فرم های پودری غربال های 3A ، 4A ، 5A و 13X برای کاربردهای خاص مناسب هستند.

Molecular غربال ها مدت هاست که به دلیل ظرفیت خشک کردنشان (حتی تا 90 درجه سانتیگراد) مشهور بوده اند و عملی بودن آنها اخیراً در فرآیندهای آلی مصنوعی نشان داده شده است. آنها معمولاً می توانند محصولات مورد نظر را از واکنش های تراکم که معمولاً توسط تعادل های نامطلوب کنترل می شوند جدا کنند. ثابت شده است که این زئولیت های مصنوعی آب ، الکل ها (از جمله متانول و اتانول) و HCl را از سیستم هایی مانند کتمین ها و تراکم آمین ها ، تراکم استر و تبدیل آلدئیدهای غیراشباع به پلی آلدئیدها حذف می کنند.

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Molecular غربال ها موادی هستند که دارای منافذ ریز دقیق و یکنواخت هستند و می توان از آنها برای جذب گازها یا مایعات استفاده کرد. معمولاً غربال های مولکولی از کانی های سیلیکات آلومینیوم تشکیل شده اند و مخلوط ها یا ترکیبات مصنوعی نیز وجود دارد. این ترکیبات دارای ساختار باز هستند که به مولکول های کوچک اجازه انتشار می دهد ، مانند: خاک رس ، شیشه متخلخل ، زغال چوب ریز متخلخل ، کربن فعال و غیره.


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Molecular غربال ها می توانند مولکول های کوچکتر از قطر منافذ خود را به کانال های داخلی منافذ جذب کنند ، در حالی که مولکول های بزرگتر را در خارج از منافذ دفع می کنند. این آنها را قادر می سازد تا عملکرد غربالگری مولکول ها را انجام دهند. البته غربال های مولکولی نه تنها وظیفه غربالگری را دارند ، بلکه نقش خاصی در افزایش توانایی واکنش دارند ، یعنی به عنوان یک "محیط" در واکنش های شیمیایی عمل می کنند و باعث پیشرفت واکنش های شیمیایی می شوند.




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